The cloth that had been around Jesus' head was rolled up, lying separate from the linen cloths.

Luke 19:20
Then another servant came and said, 'Master, here is your mina, which I have laid away in a piece of cloth.

John 11:44
The man who had been dead came out with his hands and feet bound in strips of linen, and his face wrapped in a cloth. "Unwrap him and let him go," Jesus told them.

John 19:40
So they took the body of Jesus and wrapped it in linen cloths with the spices, according to the Jewish burial custom.

John 20:6
Simon Peter arrived just after him. He entered the tomb and saw the linen cloths lying there.

And the napkin, that was about his head, not lying with the linen clothes, but wrapped together in a place by itself.